I had a new can of Minwax Polycrylic Satin and decided to try it on some scrap boards that I had painted off-white using Sherwin Williams Duration acrylic latex. A while back, I tried brushing the Polycrylic with less than satisfactory results, so I decided to try spraying it on. I sprayed it on some unfinished poplar and it went on smoothly and dried normally. Then I sprayed a coat onto the white painted wood. Again, it sprayed normally and dried to a rather pleasant satin sheen - just what I was hoping for. Unfortunately, the moment the Polycrylic hit the paint, it turned yellow. Not a tinge of yellow as you might expect from an oil based poly, but a real yellow. I did some searching on the internet and found that this is a problem that occurs frequently over white or off-white paint. I know that there are better products available to us (Target em6000 comes to mind) but I would love to understand why the Minwax Polycrylic acted this way. Any ideas?